Synthesis of selenium-containing alkyl products.
Keywords:
alkyl, selenoxo, pyrimidinone, alkyl productAbstract
We have studied the alkylation reactions of 2-selenoxo-6-methylpyrimidin-4-one with higher C4 -C9 alkyl halides. It was shown that the reaction proceeds mainly by the N3 and O4 reaction centers. We proved this by physicochemical method of analysis (IR, PMR, Mass)
References
Ergash O. Oripov, Hamid J.Nurbayev, Anvar U.Buranov. Synthesis and Plural Reactionary capabilities of the 2-Selenolumoxy-Pyrimidin-4-ones. Thirty-Fifth National Organic Chemistry Symposium of the American Chemical Society. Trinity University San Antonio Texas. June 22-26. 1997, p.31
Alkylation of polyidentical anions of 2-oxo-, -thioxo-,-selenoxo-, -methylthio-, -amino-, -6-methyl-, 2-thioxo-6-phenylpyrimidinones-4 alkyl halides with C4-C9. Ph.D. in Chem. Tashkent, 1998.
I.I.Grandberg Practical Works and Seminars in Organic Chemistry. Moscow V.Sh. 1978, pp. 148-149.
Kh.I. Nurbayev, K.A. Zakhidov, O.E. Oripov, R.A. Samiyev, H.M. Shakhidoyatov. Tautomerism and reactivity of substituted pyrimidines. Synthesis and alkylation of 6-methyl-2-selenoxopyrimidinone-4. //Uzb.chim.zhurnal, 1996. №1-2, с 96-101.
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